A stunning display by Bolivia goalkeeper Carlos Lampe denied Brazil all three points in an entertaining 0-0 draw at the Estadio Hernando Siles in La Paz.
The result has little impact on the CONMEBOL World Cup qualifying section with Brazil's position as group winners already secure and Bolivia unable to improve on their spot in ninth.
Neymar, in particular, will be left cursing the performance of Lampe as the Huachipato goalkeeper prevented him from adding to his international tally of 52 goals with a series of impressive stops.
Gabriel Jesus, Willian and Dani Alves were also denied as the hosts held firm.
Bolivia offered little attacking threat but came close to scoring on the stroke of half-time when Diego Bejarano thumped a long-range drive against the crossbar.